Anion Exchange Membrane Based on Sulfonated Poly (Styrene-Ethylene-Butylene-Styrene) Copolymers

Abstract

Sulfonated poly(styrene-ethylene-butylene-styrene) copolymer (S-SEBS) was prepared as an anion exchange membrane using the casting method. The prepared S-SEBS was further modified with sulfonic acid groups and grafted with maleic anhydride (MA) to improve the ionic conducting properties. The prepared MA-grafted S-SEBS (S-SEBS-g-MA) membranes were characterized by Fourier transform infrared red (FT-IR) spectroscopy and dynamic modulus analysis (DMA). The morphology of the S-SEBS and S-SEBS-g-MA was investigated using atomic force microscopy (AFM) analysis. The modified membranes formed ionic channels by means of association with the sulfonate group and carboxyl group in the SEBS. The electrochemical properties of the modified SEBS membranes, such as water uptake capability, impedance spectroscopy, ionic conductivity, and ionic exchange capacity (IEC), were also measured. The electrochemical analysis revealed that the S-SEBS-g-MA anion exchange membrane showed ionic conductivity of 0.25 S/cm at 100% relative humidity, with 72.5% water uptake capacity. Interestingly, we did not observe any changes in their mechanical and chemical properties, which revealed the robustness of the modified SEBS membrane.