Ethanolic Media Effect on the Susceptibility to Stress Corrosion Cracking in an X-70 Microalloyed Steel with Different Aging Treatments

Abstract

The objective of this research was to evaluate the stress corrosion cracking (SCC) of X-70 micro-alloyed steel in contact with bio-ethanol and E-50 gasohol. Environmental factors, including water (1%, 3% and 5%) and NaCl (10 mg/L and 32 mg/L), as well as two aging treatments were studied. Experimental values were obtained by the Slow Strain Rate Test (SSRT) technique, X-ray fluorescence (XRF), and tensile test according to the information reported in the literature. The results of the SSRT for the SCC determination showed that this steel in these conditions did not show evidence of SCC, which was attributed to the formation of an oxide (Fe2O3) not soluble in ethanol. The oxide layer acts as a protector preventing the formation of pitting, one of the main causes of cracks initiation in SCC.