The Influence of the Washcoat Deposition Process on High Pore Density Open Cell Foams Activation for CO Catalytic Combustion

Abstract

Spin coating was evaluated as alternative deposition technique to the commonly used dip coating procedure for washcoat deposition on high-porosity metallic substrates. By using spin coating, the washcoating of metallic open cell foams with very high pore density (i.e., 580 μm in cell diameter) was finely controlled. Catalytic performances of samples prepared with conventional dip coating and spin coating were evaluated in CO catalytic combustion in air, using palladium as active phase and cerium oxide as carrier. The incipient wetness method was used to prepare catalytic powder, which was dispersed by means of an acid-free dispersing medium. After washcoating, deposited layers were evaluated by optical microscopy and adhesion test. In comparison to dip-coated samples, the use of spin coating demonstrated better performances from both catalytic and coating quality points of view, highlighting the possibility of the industrial adoption of these supports for process intensification in several catalytic applications.