Synthesis and Characterization of Cationic Tetramethyl Tantalum(V) Complex-Reference-Cited by-同舟云学术

Synthesis and Characterization of Cationic Tetramethyl Tantalum(V) Complex

Published:2018-11-01 Issue:11 Volume:8 Page:507
ISSN:2073-4344
Container-title:Catalysts
language:en
Short-container-title:Catalysts

Author:

Dey Raju,Mohandas Janet,Samantaray Manoja,Hamieh Ali,Kavitake Santosh,Chen Yin,Abou-Hamad Edy,Cavallo Luigi,Poater Albert^ORCID,Basset Jean-Marie

Abstract

A novel method for the synthesis of the homogeneous homoleptic cationic tantalum(V)tetramethyl complex [(TaMe4)+ MeB(C6F5)3−] from neutral tantalumpentamethyl (TaMe5) has been described, by direct demethylation using B(C6F5)3 reagent. The aforesaid higher valent cationic tantalum complex was characterized precisely by liquid state 1H-NMR, 13C-NMR, and 1H-13C-NMR correlation spectroscopy.

Funder

Ministerio de Economía y Competitividad

Publisher

MDPI AG

Subject

Physical and Theoretical Chemistry,Catalysis

Link

http://www.mdpi.com/2073-4344/8/11/507/pdf

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