First Terrestrial Occurrence of Kaitianite (Ti3+2Ti4+O5) from the Upper Mantle beneath Mount Carmel, Israel

Abstract

Our nanomineralogical investigation of melt inclusions in corundum xenoliths from the Mount Carmel area, Israel, has revealed seven IMA-approved new minerals since 2021. We report here the first terrestrial occurrence of kaitianite (Ti3+2Ti4+O5). Kaitianite occurs as exsolution lamellae in tistarite (Ti2O3), in a melt inclusions together with a Ti,Al,Zr-oxide, a MgTi3+2Al4SiO12 phase, spinel, sapphirine, Ti-sulfide, alabandite, and Si-rich glass in a corundum grain (Grain 1125C2). The chemical composition of kaitianite using electron probe microanalysis is (wt%) Ti2O3 58.04, TiO2 37.82, Al2O3 2.87, MgO 0.85, ZrO2 0.10, CaO 0.02, SiO2 0.02, sum 99.73, yielding an empirical formula of (Ti3+1.78Al0.12Ti4+0.05Mg0.05)(Ti4+1.00)O5, with the Ti3+ and Ti4+ partitioned, assuming a stoichiometry of three cations and five oxygen anions pfu. Electron back-scatter diffraction reveals that kaitianite has the monoclinic C2/c γ-Ti3O5-type structure with cell parameters: a = 10.12 Å, b = 5.07 Å, c = 7.18 Å, β = 112°, V = 342 Å3, and Z = 4. Kaitianite is a high-temperature oxide phase, formed in melt pockets under reduced conditions in corundum-aggregate xenoliths derived from the upper mantle beneath Mount Carmel, Israel.