Abstract
Lithium metal batteries are one of the more promising replacements for lithium-ion batteries owing to their ability to reach high energy densities. The main problem limiting their commercial application is the formation of dendrites, which significantly reduces their durability and renders the batteries unsafe. In the present work, we used a single-ion conducting gel polymer electrolyte based on a poly(ethylene-ran-butylene)-block-polystyrene (SEBS) block copolymer, which was functionalized with benzenesulfonylimide anions and plasticized by a mixture of ethylene carbonate and dimethylacetamide (SSEBS-Ph-EC-DMA), with a solvent uptake of 160% (~12 solvent molecules per one functional group of the membrane). The SSEBS-Ph-EC-DMA electrolyte exhibits an ionic conductivity of 0.6 mSm∙cm−1 at 25 °C and appears to be a cationic conductor (TLi+ = 0.72). SSEBS-Ph-EC-DMA is electrochemically stable up to 4.1 V. Symmetrical Li|Li cells; further, with regard to SSEBS-Ph-EC-DMA membrane electrolytes, it showed a good performance (~0.10 V at first cycles and <0.23 V after 700 h of cycling at ±0.1 mA∙cm−2 and ±0.05 mAh∙cm−2). The LiFePO4|SSEBS-Ph-EC-DMA|Li battery showed discharge capacity values of 100 mAh∙g−1 and a 100% Coulomb efficiency, at a cycling rate of 0.1C.
Funder
Ministry of Science and Higher Education of the Russian Federation
Subject
Process Chemistry and Technology,Chemical Engineering (miscellaneous),Bioengineering
Cited by
3 articles.
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