1-(2-(3,5-Di-tert-butyl-4-hydroxyphenyl)-2-oxoethyl) Quinolin-1-ium Bromide

Author:

Rusew Rusi1ORCID,Iliev Kostadin1,Kurteva Vanya2ORCID,Shivachev Boris1ORCID

Affiliation:

1. Institute of Mineralogy and Crystallography “Acad. Ivan Kostov”, Bulgarian Academy of Sciences, Acad. G. Bonchev Street, bl. 107, 1113 Sofia, Bulgaria

2. Institute of Organic Chemistry with Centre of Phytochemistry, Bulgarian Academy of Sciences, Acad. G. Bonchev Street, bl. 9, 1113 Sofia, Bulgaria

Abstract

The title compound 1-(2-(3,5-di-tert-butyl-4-hydroxyphenyl)-2-oxoethyl) quinolin-1-ium bromide was obtained in good yield by a facile one-pot, one-step synthetic procedure involving quinoline and an aromatic α-bromo ketone. The product was isolated using hot recrystallization from acetone/acetonitrile solution and characterized using powder and single-crystal XRD, 1D and 2D NMR, DSC, FT-IR, and HRMS analyses.

Funder

Bulgarian National Science Fund

Publisher

MDPI AG

Reference43 articles.

1. Abboud, J.-L.M., Notario, R., Bertrán, J., and Solà, M. (1993). Progress in Physical Organic Chemistry, John Wiley & Sons.

2. Electronic effects on the Menshutkin reaction. A complete kinetic and thermodynamic dissection of alkyl transfer to 3-and 4-substituted pyridines;Arnett;J. Am. Chem. Soc.,1980

3. Analysis of solvent effects on the Menshutkin reaction;Sola;J. Am. Chem. Soc.,1991

4. Solvent effects on methyl transfer reactions. 1. The Menshutkin reaction;Castejon;J. Am. Chem. Soc.,1999

5. Application of quinoline derivatives in third-generation photovoltaics;Lewinska;J. Mater. Sci. Mater. Electron.,2021

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