Nb-Based Catalysts for the Valorization of Furfural into Valuable Product through in One-Pot Reaction

Author:

Maderuelo-Solera Rocío1ORCID,Torres-Olea Benjamín1,Jiménez-Gómez Carmen Pilar1,Moreno-Tost Ramón1ORCID,García-Sancho Cristina1ORCID,Mérida-Robles Josefa1,Cecilia Juan Antonio1ORCID,Maireles-Torres Pedro1ORCID

Affiliation:

1. Department of Inorganic Chemistry, Crystallography and Mineralogy, Málaga University, 29071 Málaga, Spain

Abstract

Nb-based catalysts supported on porous silica with different textural properties have been synthesized, characterized, and tested in the one-pot reaction of furfural to obtain valuable chemicals. The catalytic results reveal that the presence of fluoride in the synthesis, which limits the growing of the porous silica, limits diffusional problems of the porous silica, obtaining higher conversion values at shorter reaction times. On the other hand, the incorporation of NbOx species in the porous silica provides Lewis acid sites and a small proportion of Brönsted acid sites, in such a way that the main products are alkyl furfuryl ethers, which can be used as fuel additives.

Funder

Spanish Ministry of Science and Innovation

FEDER (European Union) funds

Ministerio de Educación y Formación Profesional

Publisher

MDPI AG

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