Concentrations of Major and Trace Elements within the Snowpack of Tyumen, Russia

Abstract

A study on the composition of snow allowed for a quantitative determination of pollutants deposited from the atmosphere. Concentrations of dissolved (<0.45 μm) and particulate fractions of 62 chemical elements were determined by ICP–MS and ICP–AES in 41 samples of snow from Tyumen (Russia). The background sites were characterized by a predominance of the dissolved phase of elements, except for Al, Sn, Cr, Co and Zr. The increased concentrations of dissolved Cd, Cu, Zn, Pb, Ni, As and Mo can be explained by a long-range atmospheric transport from the sources located in the Urals. The urban sites showed multiple increases in particulate depositions and a predominance of the particulate phase, with a high degree of enrichment in many heavy metals. Sources of trace elements were determined according to the enrichment factor (EF). Highly enriched elements (Pb, Sb, Cd, Ag, Mo, As, Zn and Cu) with an EF > 100 were emitted from anthropogenic sources. According to the potential ecological risk index (RI), the worst ecological conditions were identified in Tyumen’s historical center, industrial zone and along roads with the heaviest traffic. The data obtained in the present study allowed us to identify the most polluted parts of the city, which are located in the center and along the roads with the most intensive traffic. This research could offer a reference for the atmospheric pollution prevention and control in Tyumen.