Mineralogical and Chemical Tracing of Dust Variation in an Underground Historic Salt Mine

Abstract

The aim of this study was to investigate the causes of the evolution of atmospheric dust composition in an open-to-public subterranean site (UNESCO-recognized historic mine) at increasing distances from the air intake. The role of the components imported with atmospheric air from the surface was compared with natural and anthropogenic sources of dust from inside the mine. Samples of deposited dust were directly collected from flat surfaces at 11 carefully selected sites. The morphological, mineralogical, and chemical characteristics were obtained using scanning electron microscopy (SEM), X-ray diffraction (XRD), and inductively coupled plasma spectroscopy (ICP). The study showed that the air in the underground salt mine was free of pollutants present in the ambient air on the surface. Most of the components sucked into the mine by the ventilation system from the surface (regular dust, particulate matter, gaseous pollutants, biogenic particles, etc.) underwent quick and instantaneous sedimentation in the close vicinity of the air inlet to the mine. The dust settled in the mine interior primarily consisted of natural geogenic particles, locally derived from the weathering of the host rock (halite, anhydrite, and aluminosilicates). This was confirmed by low values of enrichment factors (EF) calculated for minor and trace elements. Only one site, due to the tourist railroad and the associated local intensive tourist traffic, represented the anthropogenic sources of elevated concentrations of ferruginous particles and accompanied metals (P, Cr, Mn, Co, Ni, Cu, As, Mo, Cd, Sn, Sb, Pb, and W). The gravitational deposition of pollutants from these sources limits the effects of the emissions to the local range. The used methodology and the results are universal and might also apply to other mines, caves, or underground installations used for museums, tourists, or speleotherapeutic purposes.