Carbon-Based FET-Type Gas Sensor for the Detection of ppb-Level Benzene at Room Temperature

Abstract

Benzene, as a typical toxic gas and carcinogen, is an important detection object in the field of environmental monitoring. However, it remains challenging for the conventional resistance-type gas sensor to effectively detect low-concentration (ppb-level) benzene gas molecules, owing to their insufficient reaction activation energy, especially when operating at room temperature. Herein, a field-effect transistor (FET)-type gas sensor using carbon nanotubes as a channel material is proposed for the efficient detection of trace benzene, where carbon nanotubes (CNTs) with high semiconductor purity act as the main channel material, and ZnO/WS2 nanocomposites serve as the gate sensitive material. On the basis of the remarkable amplification effect in CNTs-based FET, the proposed gas sensor manifests desirable sensitive ability with the detection limit as low as 500 ppb for benzene even working at room temperature, and the sensor also exhibits fast response speed (90 s), high consistency with a response deviation of less than 5%, and long-term stability of up to 30 days. Furthermore, utilizing Tenax TA as the screening unit, the as-proposed gas sensor can achieve the feasible selective detection of benzene. These experimental results demonstrate that the strategy proposed here can provide significant guidance for the development of high-performance gas sensors to detect trace benzene gas at room temperature.