Comparison of Surface and Spectral Properties of Optical Sensor Layers Prepared by Spin/Spray Coating and Printing Techniques

Author:

Dimitrušev Nena123,Nedeljko Polonca2,Mabes Raj A. F. P. Allwin245,Lobnik Aleksandra23

Affiliation:

1. Messer Slovenija, Jugova ulica 20, 2342 Ruše, Slovenia

2. Institute for Environmental Protection and Sensors, Beloruska 7, 2000 Maribor, Slovenia

3. Faculty of Mechanical Engineering, Centre of Sensor Technology, University of Maribor, Smetanova 17, 2000 Maribor, Slovenia

4. Department of Environmental Science, Jožef Stefan Institute, Jamova 39, 1000 Ljubljana, Slovenia

5. Jožef Stefan International Postgraduate School, Jamova 39, 1000 Ljubljana, Slovenia

Abstract

This study investigated the surface properties of optical sensor layers prepared using sol-gel technology and their response to dissolved NH3. A glass substrate was used to fabricate the optical sensor layers. The sol-gel solution was applied to the glass substrate using three different techniques: spin coating (SC), inkjet printing (IP), and spray coating (SP). In this work, we have attempted to investigate the effects of the different techniques for producing the sensor layers and to determine their response in the presence of ammonia. The surface properties (surface free energy—SFE and surface chemical composition—XPS) and spectral properties (response to ammonia and real-time response) of the prepared optical sensor layers were characterised. The results show that the sensor layers prepared by different techniques have similar SFE and XPS values, but different responses to dissolved NH3 solution and different responses in real-time measurements (exposure to fresh fish). Sensor layers prepared with a spray coating (SP) are the most responsive, the most sensitive, and have a higher response over time and the biggest colour change compared to SC and IP sensor layers.

Funder

the Ministry of Education, Science and Sport, Republic of Slovenia

Optical chemical/biosensor systems

the Marie Skłodowska-Curie Action Global Mercury Observation and Training Network in Support to the Minamata Convention

Publisher

MDPI AG

Subject

Physical and Theoretical Chemistry,Analytical Chemistry

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