Carbon Fibers and Graphite as Pore-Forming Agents for the Obtention of Porous Alumina: Correlating Physical and Fractal Characteristics

Abstract

Porous alumina ceramics with different porosities were prepared via atmospheric pressure sintering using a sacrificial template method with alumina powder as the raw material and carbon fiber (CF) and graphite as pore-forming agents. The effects of the contents and ratios of the pore-forming agents and the aspect ratios of CF on the microstructure, mechanical properties, pore size, and pore-size distribution of the porous alumina samples were investigated. In addition, the surface fractal dimension (Ds) of porous alumina samples with different pore-forming agents was evaluated based on the mercury intrusion porosimetry data. The pore-size distribution of the prepared porous alumina samples showed single, double, or multiple peaks. The pore structure of the samples maintained the fibrous shape of the original CF and the flake morphology of graphite with a uniform pore-size distribution, but the pore structure and morphology were different. With the increase in the content of the pore-forming agent, the porosity of the samples gradually increased to a maximum of 63.2%, and the flexural strength decreased to a minimum of 12.36 MPa. The pore structure of the porous alumina samples showed obvious fractal characteristics. Ds was closely related to the pore structure parameters of the samples when the content of the pore-forming agent was 70 vol.%. It decreased with an increase in the sample porosity, most probable pore size and median pore size, but increased with an increase in the sample flexural strength.