Analysis of the Charge Density Variation Caused by the Physical Properties of the Electrodes of Lithium-Ion Batteries

Abstract

The detection and characterization of electrode performance is a key problem of lithium-ion batteries. The physical properties of the electrodes affect the charge density during the life of a battery. The charge density is difficult to monitor because of the complexity of the charge distribution. In this paper, a visualized fractional derivative order (FDO) is used to characterize the charge distribution and to reveal variations in the charge density associated with the physical properties of the electrode. Instantaneous discharge datasets collected at different aging stages of batteries are used to identify the FDO in the fractional derivative model. The results show that the FDO has a strong correspondence with the charge density. As the charge density decreases, the charge mobility gradually increases due to changes in the charge distribution. Moreover, this paper finds that the capacity recovery effect is closely related to the mutation of the charge density and uses the FDO to explain the charge accumulation at the sharp edges of the electrodes. The analysis of the charge density variation caused by the physical properties of the electrodes provides guidance for the detection of the electrode performance and the design of the electrode microstructure.