Co-Combustion Behavior of Paper Sludge Hydrochar and Pulverized Coal: Low Rank Coal and Its Product by Hydrothermal Carbonization

Abstract

In this paper, the combustion behavior of low rank coal and its product after hydrothermal carbonization with paper sludge hydrochar were studied. The Raman technique was used to compare the structural differences between raw coal and the product. Thermogravimetric analysis was employed to conduct experiments of single sample and their mixtures with different proportions at a heating rate of 20 °C/min, the activation energy of chemical reactions was calculated. The results showed that upgraded product had higher carbon ordering degree than raw coal and the ignition temperature and burnout temperature of the product were advanced. Compared with raw coal, the combustion characteristic parameters C and S of the product were higher, indicating that its combustibility was better. As for the mixture, when the paper sludge hydrochar ratio was not more than 10%, the mixed fuel combustion curve was still similar to coal curve. After the paper sludge hydrochar ratio exceeded 10%, the activation energy of the mixed combustion reaction of paper sludge hydrochar and upgraded coal was lower than that of raw coal and paper sludge hydrochar. These results indicated that the mixture of upgraded coal and paper sludge hydrochar as mixed fuel was a better option.