An Innovative Approach for Restoring the Mechanical Properties of Thermoplastic-Matrix Nanocomposite by the Use of Partially Polymerized Cyclic Butylene Terephthalate

Abstract

This work is focused on the production of a smart material from cyclic butylene-terephthalate (CBT), characterized by the built-in capability to recover its damage, through the catalyzed ring opening polymerization (ROP) of its oligomers; in particular, molten CBT, after filling the damaged zone, can be converted into poly-butylene terephthalate (PBT), thus promoting a join of the broken surfaces and fixing the crack. To obtain a material with self-healing potential, the production of a partially polymerized system is required. For this purpose, two solutions were studied: the first one involved the use of two catalysts with different activation times, whereas the second solution implied the intercalation of the faster catalyst inside the nanoclay lamellae. Since the intercalation allowed slowing the activation of the catalyst, residual CBT can be converted in a second step. Mechanical properties of partially reacted PBT samples and their healing ability were checked by flexural analyses; in order to promote the healing process, samples were notched to simulate partial damage and left in oven for different times and temperatures, to allow the activation of the unreacted catalyst with the consequent ROP of the residual CBT; flexural tests on samples after healing showed a good recovery of mechanical properties.