Mineralogical and Geochemical Composition of Late Permian Coals from Dengfeng Coalfield, North China: Conversion of Clay Minerals in Coal during Coalification

Abstract

Dengfeng Coalfield represents a significant coalfield in Henan Province, North China. It is therefore essential to gain an understanding of the mineralogy and geochemistry of the Dengfeng coal, both from a geochemical perspective and in terms of the wider environmental context. In this study, a total of 27 coal bench samples were collected from the No. II1 coal of the Dengfeng Coalfield. The mineral species and major elements were quantitatively analysed using the X-ray diffraction and X-ray fluorescence methods, respectively. The minerals in the Dengfeng coal are dominated by ammonian illite and kaolinite with average contents of 3.73% and 7.47%, respectively. These are followed by calcite (2.74% on average) and ankerite (0.49%). The mean value of the kaolinite Hinkley index, which is a quantitative measure of kaolinite crystallinity, is 1.26. This suggests that kaolinite formation is primarily driven by diagenetic recrystallisation. The ammonian illite exhibits an average d001 of 10.2995 Å, indicative of a prevalence of NH4+ interlayer cations, with K+ also present in notable quantities. The ratio of NH4⁺ to (NH4⁺ + K⁺) has an average value of 0.90, which is indicative of the predominance of NH4⁺. The mean value of the illite Kübler index, which is a quantitative measure of illite crystallinity, is 0.264. This suggests that the diagenetic conditions correspond to the rank of the Dengfeng coal. The kaolinite present in the Dengfeng coal is suggested to have been derived from terrigenous detritus and subsequently subjected to diagenetic recrystallisation, resulting in a relatively high Hinkley index. The ammonian illite in the Dengfeng coal was predominantly formed through the conversion of the precursor kaolinite, with the influence of seawater during peat accumulation favouring the conversion of kaolinite to ammonian illite.