Author:
Xu Wangqiong,Li Hongkai,Zheng Yonghui,Lei Weibin,Wang Zhenguo,Cheng Yan,Qi Ruijuan,Peng Hui,Lin Hechun,Yue Fangyu,Huang Rong
Abstract
Ti-doped truncated octahedron LiTixMn2-xO4 nanocomposites were synthesized through a facile hydrothermal treatment and calcination process. By using spherical aberration-corrected scanning transmission electron microscopy (Cs-STEM), the effects of Ti-doping on the structure evolution and stability enhancement of LiMn2O4 are revealed. It is found that truncated octahedrons are easily formed in Ti doping LiMn2O4 material. Structural characterizations reveal that most of the Ti4+ ions are composed into the spinel to form a more stable spinel LiTixMn2−xO4 phase framework in bulk. However, a portion of Ti4+ ions occupy 8a sites around the {001} plane surface to form a new TiMn2O4-like structure. The combination of LiTixMn2−xO4 frameworks in bulk and the TiMn2O4-like structure at the surface may enhance the stability of the spinel LiMn2O4. Our findings demonstrate the critical role of Ti doping in the surface chemical and structural evolution of LiMn2O4 and may guide the design principle for viable electrode materials.
Funder
National Natural Science Foundation of China
Shanghai Science and Technology Innovation Action Plan
National Key Research and Development Program of China
Subject
General Materials Science,General Chemical Engineering
Cited by
17 articles.
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