Crystal Structure and Microwave Dielectric Property of xMgO-SiO2 (x = 1~2) System for 5G Applications

Author:

Wang Yan1,Li Jiajing1,Zhu Haipeng1,Wang Qilei1,Sun Tulai2,Ni Tao1,Lin Yanghong1,Liu Yu1,Mao Minmin1,Hu Ji1,Liu Bing1ORCID,Bafrooei Hadi Barzegar13,Ma Zhongyan4,Ren Yingjie4,Shi Feng5,Taheri-Nassaj Ehsan6,Wang Dawei7ORCID,Song Kaixin1ORCID

Affiliation:

1. College of Electronics and Information, Hangzhou Dianzi University, Hangzhou 310018, China

2. Center for Electron Microscopy, State Key Laboratory Breeding Base of Green Chemistry Synthesis Technology, Zhejiang University of Technology, Hangzhou 310014, China

3. Department of Materials Science and Engineering, School of Engineering, Meybod University, Yazd 89616-99557, Iran

4. Institute of Communication Materials, Zhejiang Wazam New Materials Co., Ltd., Hangzhou 311121, China

5. School of Materials Science and Engineering, Qilu University of Technology (Shandong Academy of Sciences), Jinan 250353, China

6. Department of Materials Science and Engineering, Tarbiat Modares University, Tehran 14115-143, Iran

7. School of Instrumentation Science and Engineering, Harbin Institute of Technology, Harbin 150080, China

Abstract

Mg2SiO4 and MgSiO3 ceramics with superior microwave dielectric properties are considered to be promising candidates for 5G applications. However, a slight deviation from the stoichiometric Mg/Si ratio will significantly influence their microwave dielectric properties, which will hinder their practical applications. In this work, the xMgO-SiO2 (x = 1~2) ceramics were synthesized by a solid-state reaction method. The influence of the Mg/Si ratio x on the crystalline phase, microstructure, and microwave dielectric properties was investigated through X-ray diffraction (XRD), a scanning electron microscope (SEM), and the resonant cavity method. The XRD patterns revealed the coexistence of Mg2SiO4 and MgSiO3 within the x range of 1~2, which was further demonstrated by the energy-dispersive X-ray spectra. The SEM images show a typical polycrystalline morphology of ceramics with an inhomogeneous grain size distribution. It is found that the microwave dielectric properties fluctuate at both sides of the x range while those remain relatively stable with minor changes at the intermediate components, indicating an obvious low composition dependence helpful for practical applications. Further, a demonstrator of a microstrip patch antenna for 5G applications using the 1.5MgO-SiO2 ceramic was designed and fabricated, and a return loss of −16.2 dB was demonstrated, which demonstrated the potential applications.

Funder

National Natural Science Foundation of China

Natural Science Foundation of Jiangsu Higher Education Institutions of China

Department of Science and Technology of Zhejiang province on the “sharp soldiers” and “leading geese” research and development research planning project

Publisher

MDPI AG

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science,General Chemical Engineering

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