Affiliation:
1. Fakultät Für Chemie und Mineralogie, Universität Leipzig, Johannisallee 29, D-04103 Leipzig, Germany
Abstract
Three molecular sulfido complexes containing a Cd-S-Sn structure motive, [{(tmeda)Cd}3(SnPh)2S6] (1), [{(tmeda)Cd}2(SnPh2)2S4] (2) and [{(iPr3P)Cd}3Cd4(SnPh2)6S13] (3), have been synthesized and characterized by single-crystal X-ray diffraction. So far, 2 is the first cadmium tin sulfido complex soluble in common organic solvents. Analysis by 113Cd and 119Sn NMR spectroscopy shows a slow rearrangement in solution, while spin coupling between the nuclei can be used to identify the species in solution. Thermolysis of 2 results in CdS and SnS as solid thermolysis products.
Funder
European Regional Development Fund
Subject
Inorganic Chemistry,Condensed Matter Physics,General Materials Science,General Chemical Engineering
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