Functionalization and Coordination Effects on the Structural Chemistry of Pendant Arm Derivatives of 1,4,7-trithia-10-aza-cyclododecane ([12]aneNS3)

Author:

Caltagirone Claudia1ORCID,Aragoni Maria Carla1ORCID,Arca Massimiliano1ORCID,Blake Alexander John2,Demartin Francesco3ORCID,Garau Alessandra1ORCID,Podda Enrico4ORCID,Pop Alexandra5,Lippolis Vito1ORCID,Silvestru Cristian5ORCID

Affiliation:

1. Dipartimento di Scienze Chimiche e Geologiche, Università degli Studi di Cagliari, S.S. 554 Bivio per Sestu, 09042 Monserrato (CA), Italy

2. School of Chemistry, University of Nottingham, University Park, Nottingham NG7 2RD, UK

3. Dipartimento di Chimica, Università degli Studi di Milano, 20133 Milano, Italy

4. Centro Servizi di Ateno per la Ricerca-CeSAR, Università degli Studi di Cagliari, S.S. 554 Bivio per Sestu, 09042 Monserrato (CA), Italy

5. Supramolecular Organic and Organometallic Chemistry Centre, Department of Chemistry, Faculty of Chemistry and Chemical Engineering, Babes-Bolyai University, Str. Arany Janos 11, 400028 Cluj-Napoca, Romania

Abstract

The effect of different pendant arms on the structural chemistry of the 1,4,7-trithia-10-aza-cyclododecane ([12]aneNS3) macrocycle is discussed in relation to the coordination chemistry of all known functionalized derivatives of [12]aneNS3, which have been structurally characterized.

Publisher

MDPI AG

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science,General Chemical Engineering

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