A Comparative Study on Gemological Characteristics and Color Formation Mechanism of Moqi Agate, Inner Mongolia Province, China
Author:
Zhang Sixue1,
Cui Li1,
Guo Qingfeng1ORCID,
Li Niu1,
Liu Yang1,
Rao Yinghua1,
Liao Libing2
Affiliation:
1. School of Gemology, China University of Geosciences, Beijing 100083, China
2. Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Sciences and Technology, China University of Geosciences, Beijing 100083, China
Abstract
Agate attracts the attention of gem mineralogists because of its variable colors. The color of agate is closely related to its naming and classification, so it is necessary to study the color and mineral origin of agate. In this paper, the mineralogical characteristics and color origin of red, yellow and green Moqi agates from Inner Mongolia were systematically studied by means of Fourier transform infrared spectrometer, Raman spectrometer, X-ray powder diffractometer, electron probe microanalyzer and ultraviolet–visible spectrophotometer. It is found that the color of Moqi agate is related to the minerals and trace elements contained in it, and is associated with the electron transition or charge transfer of Fe ions in the contained minerals. Green agate has the highest Fe content, and its color is caused by celadonite inclusions. The red and yellow color in Moqi agate is mainly caused by hematite and goethite, while red agate contains more Fe than yellow agate. Raman spectroscopy and X-ray diffraction analysis show that the content of moganite in Moqi agate is 0–30%. It is calculated that the crystallinity of Moqi agate is 1.5–3.5. This work provides a theoretical basis for future research on the identification of Moqi agate.
Funder
National Science and Technology Infrastructure—The National Infrastructure of Mineral, Rock and Fossil Resources for Science and Technology
Program for Data Integration and Standardization in Geological Science and Technology from MOST, China
Subject
Inorganic Chemistry,Condensed Matter Physics,General Materials Science,General Chemical Engineering
Reference32 articles.
1. Classification of Agate;Cai;China Nonmetal Min. Ind. Guide,2000
2. Xie, T. (2014). Study on Coloration Mechanism and Structural Genesis of “Warring States Red” Agate in Fuxin, Liaoning. [Master’s Thesis, China University of Geosciences (Beijing)].
3. Occurrence and distribution of “moganite” in agate/chalcedony: A combined micro-Raman, Rietveld, and cathodoluminescence study;Nasdala;Contrib. Mineral. Petrol.,1998
4. Amethyst, agate, and calcite ‘skunks’ from Uruguay;Currier;Rocks Miner.,1997
5. Agates from Western Australia Found in a 3,480-Million-Year-Old Host Rock;Moxon;Rocks Miner.,2010
Cited by
1 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献