Photocatalytic Degradation of Textile Orange 16 Reactive Dye by ZnO Nanoparticles Synthesized via Green Route Using Punica Granatum Leaf Extract

Author:

Al-Zahrani Salma A.1,Patil Mallikarjunagouda B.2ORCID,Mathad Shridhar N.3ORCID,Patil Arun Y.4ORCID,Otaibi Ahmed A.1,Masood Najat1,Mansour Dorsaf1,Khan Anish5ORCID,Manikandan A.6ORCID,Syafri Edi7ORCID

Affiliation:

1. Chemistry Department, Faculty of Science, University of Ha’il, P.O. Box 2440, Ha’il 81451, Saudi Arabia

2. Bharat Ratna Prof. CNR Rao Research Centre, Basaveshwar Science College, Bagalkot 587101, Karnataka, India

3. Department of Engineering Physics, K.L.E Institute of Technology, Hubballi 580027, Karnataka, India

4. School of Mechanical Engineering, KLE Technological University, Vidya Nagar, Hubballi 580031, Karnataka, India

5. Center of Excellence for Advanced Materials Research, King Abdulaziz University, P.O. Box 80203, Jeddah 21589, Saudi Arabia

6. Department of Chemistry, Bharath Institute of Higher Education and Research (BIHER), Bharath University, Chennai 600073, Tamil Nadu, India

7. Department of Agricultural Technology, Politeknik Pertanian Negeri Payakumbuh, Payakumbuh 26271, West Sumatra, Indonesia

Abstract

Since it does not use any dangerous chemicals and is a simple, low-cost process, the green synthesis approach for nanoparticle creation has several benefits compared to the physical and chemical synthesis routes. The current study describes an environmentally friendly synthesis of zinc oxide (ZnO) nanoparticles (NPs) using an extract of Punica granatum plant leaves. Fourier-transform infrared spectroscopy (FTIR), ultraviolet-visible spectrophotometer (UV-Vis), field-emission scanning electron microscopy (FESEM), energy-dispersive X-ray spectroscopy, and X-ray diffraction techniques were used to characterize the morphology, composition, and structural properties of the synthesized zinc oxide nanoparticles. The XRD pattern reveals that the ZnO nanoparticles are crystalline and have a diameter of 20 nm. According to the FESEM studies, the ZnO-NPs have sizes ranging from 50 to 100 nm on average and are almost spherical. When exposed to direct sunlight, the produced ZnO-NPs demonstrate impressive photocatalytic oxidation of textile Orange 16, a reactive dye. As a result, our research advances the development of a green photocatalyst for the removal of harmful dyes from water.

Funder

Scientific Research Deanship at the University of Ha’il-Saudi Arabia

Publisher

MDPI AG

Subject

Inorganic Chemistry,Condensed Matter Physics,General Materials Science,General Chemical Engineering

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