In-Situ SERS Detection of Hg2+/Cd2+ and Congo Red Adsorption Using Spiral CNTs/Brass Nails

Abstract

Brass spiral nails were functionalized with CoFe2O4 nanoparticles and utilized as a substrate for the growth of extremely long CNTs with helical structures and diameters smaller than 20 nm. Different methods were used to characterize the grown CNTs’ structures and morphologies. The characteristic Raman peaks of CNTs were amplified four times after being uploaded on the spiral nail, making the substrates for surface-enhanced Raman spectroscopy (SERS) more sensitive. To detect Hg2+ and Cd2+ at concentrations ranging from 1 to 1000 ppb, a CNT/spiral brass nail was used as a SERS substrate. The proposed sensor demonstrated high sensitivity and selectivity between these heavy metal ions. As a result, the proposed CNTs/spiral brass sensor can be an effective tool for identifying heavy metal ions in aqueous solutions. In addition, Congo red (CR) adsorption as a function of initial dye concentration and contact time was investigated. For CR dye solutions with concentrations of 5, 10, and 20 mg/L, respectively, the highest removal percentage was determined to be ~99.9%, 85%, and 77%. According to the kinetics investigation, the pseudo-first-order and pseudo-second-order models effectively handle CR adsorption onto CNTs/spiral nails. The increase in the dye concentration from 5 ppm to 20 ppm causes the rate constant to drop from 0.053 to 0.040 min−1. Therefore, our sample can be employed for both the effective degradation of CR dye from wastewater and the detection of heavy metals.