Comparison of Physicochemical Properties of Silver and Gold Nanocomposites Based on Potato Starch in Distilled and Cold Plasma-Treated Water

Abstract

Nanometal-containing biocomposites find wide use in many industries and fields of science. The physicochemical properties of these materials depend on the character of the polymer, the size and shape of the metallic nanoparticles, and the interactions between the biopolymer and the nanoparticles. The aim of the work was to synthesise and study the effect of plasma-treated water on the properties of the obtained metallic nanoparticles as well as the physicochemical and functional properties of nanocomposites based on potato starch. The metallic nanoparticles were synthesised within a starch paste made in distilled water and in distilled water exposed to low-temperature, low-pressure plasma. The materials produced were characterised in terms of their physicochemical properties. Studies have shown that gold and silver nanoparticles were successfully obtained in a matrix of potato starch in distilled water and plasma water. SEM (Scanning Electron Microscopy) images and UV-Vis spectra confirmed the presence of nanosilver and nanosilver in the obtained composites. On the basis of microscopic images, the size of nanoparticles was estimated in the range from 5 to 20 nm for nanoAg and from 15 to 40 nm for nanoAu. The analysis of FTIR-ATR spectra showed that the type of water used and the synthesis of gold and silver nanoparticles did not lead to changes in the chemical structure of potato starch. DLS analysis showed that the nanoAg obtained in the plasma water-based starch matrix were smaller than the Ag particles obtained using distilled water. Colour analysis showed that the nanocomposites without nanometals were colourless, while those containing nanoAg were yellow, while those with nanoAu were dark purple. This work shows the possibility of using plasma water in the synthesis of nanometals using potato starch, which is a very promising polysaccharide in terms of many potential applications.