Dissociative Ionization of the CHBr2Cl Molecule in 800 nm and 400 nm Femtosecond Laser Fields

Abstract

The dissociative ionization of CHBr2Cl molecules in femtosecond laser fields at 800 nm and 400 nm is investigated to enhance the comprehension of ultrafast dynamics phenomena. The kinetic energy distribution of the resulting ions following photo-dissociation is analyzed using time-of-flight mass spectrometry in combination with DC-sliced ion velocity map imaging. The findings from the experimental study indicate that the presence of low kinetic energy components is attributed to the dissociative ionization processes of CHBr2Cl molecules. The complexity of individual dissociation pathways remains unaffected by the laser fields but is determined by factors such as bond energy, ionization energy of neutral groups, and charge distribution. In the case of 400 nm laser fields, distinct elimination channels enable CHBr2Cl+ ions to circumvent the transition state, leading to the formation of BrCl+ and Br2+ fragments.