Carbon Monoxide Detection Based on the Carbon Nanotube-Coated Fiber Gas Sensor

Abstract

Accurate detection of the internal decomposition components of SF6 electrical equipment plays an important role in the evaluation of equipment status. However, gas samples are usually taken out for detection at present, which makes it difficult to understand the real situation inside the equipment. In this paper, a carbon nanotube-coated fiber gas sensor is proposed, which has the potential to be applied as a built-in gas sensor. The fiber loop ring-down (FLRD) gas detection system based on the carbon nanotube-coated fiber gas sensor was built, and the detectable decomposition components among the four typical SF6 decomposition components of SO2, SO2F2 and SOF2 and CO were analyzed. The results showed that the fiber gas sensor was most sensitive to CO. Based on density functional theory, it was found that single-walled carbon nanotubes had the best adsorption effect on CO molecules under the same conditions, with the adsorption energy reaching −0.150 Ha. The detection performance of the system for CO was studied, and the results showed that there was a good linear relationship between CO concentration and ring-down time: R2 was 0.984, the maximum inversion error of 0~200 ppm CO was 1.916 ppm, and the relative error was 4.10%. The sensitivity of the system was 0.183 ns/ppm, and the detection limit of the system was 19.951 ppm. The system had good stability, with the standard deviation of single-point repeatability being 0.00356, and the standard deviation of the long period of the experiment being 0.00606. The research results provide a new idea for the detection of SF6 decomposition components, and lay the foundation for the component detection method of built-in fiber sensor of SF6 electrical equipment.