Controlling Plasmon Resonance of Gold and Silver Nanoparticle Arrays with Help of Liquid Crystal

Abstract

The tunability of plasmonic resonances in gold and silver nanosphere arrays on a glass substrate, embedded in a liquid crystal matrix, was explored. The calculations involving the finite element method revealed that the optical properties of these arrays can be modulated by reorienting the liquid crystal. When the liquid crystal director was reoriented between planar and homeotropic configurations in the plane containing the incident wave polarization vector, the plasmonic resonance wavelength shifted within an approximately 100 nm range. A reduced shift of about 40 nm was observed when the reorientation occurred in the plane perpendicular to the polarization. Both metal nanosphere arrays showed notable near-field amplification. Gold achieved up to 18 times the amplification of the incident wave electric field, while silver reached 16 times but showed a remarkable 40 times amplification at the inter-band transition resonance wavelength. This research underscores the potential of using liquid crystal reorientation for controlling the plasmonic lattice resonance in metal nanosphere arrays, opening up new possibilities for adaptable plasmonic devices.