Synthesis of Aluminium Nitride-Based Coatings on Mild Steel Substrates Utilising an Integrated Laser/Sol–Gel Method

Abstract

The field of protective coatings for industrial applications is continuously evolving, driven by a need for materials that offer exceptional hardness, enhanced wear resistance, and low friction coefficients. Conventional methods of coating development, such as physical vapour deposition (PVD) and chemical vapour deposition (CVD), often face challenges like the necessity of vacuum conditions, slow growth rates, and weak substrate adhesion, leading to inadequate interface bonding. This study introduces a novel approach utilising an integrated laser/sol–gel method for synthesising aluminium nitride (AlN) coatings on EN43 mild steel substrates which overcomes these limitations. The technique employs a high-intensity diode laser with optimal power and translation speeds to consolidate a pre-applied thin layer of sol–gel slurry consisting of aluminium hydroxide, graphite, and urea on the substrate. Chemical thermodynamic calculations were used to predict the slurry composition, along with identifying the critical temperature range and the essential enthalpy needed for the synthesis of aluminium nitride. A three-dimensional heat transfer model was developed to predict the important process parameters, such as scanning speed and laser power density, required to achieve the temperature ranges necessary for a successful deposition process. Optical and scanning electron microscopy techniques were used to examine the surface morphology and microstructure of the coating. Elemental energy-dispersive X-ray spectroscopy and an X-ray diffraction analysis confirmed the synthesis of an aluminium nitride coating with a thickness ranging from 4 to 5 µm. Furthermore, the detection of sub-micron crystalline aluminium nitride structures yielding a metal matrix composite interlayer was indicative of strong metallurgical bonding. Microhardness testing indicated a hardness value of approximately 876 HV. The coated samples with the highest quality exhibited a surface roughness, Ra, ranging from 1.8 to 2.1 µm. Additionally, the coatings demonstrated an exceptionally low coefficient of friction, recorded at less than 0.1. These results represent a significant step forward in this field, offering a cost-effective, efficient, and scalable solution for producing high-quality coatings with superior performance characteristics.