Advanced Ceramics with Dual Functions of Healing and Decomposition

Author:

Sekine Nobuhide1ORCID,Nakajima Yasushi2,Kamo Takahiro2,Ito Masahiro2,Nakao Wataru3

Affiliation:

1. Graduate School of Engineering, Yokohama National University, Tokiwadai 79-5, Hodogaya-ku, Yokohama 240-8501, Kanagawa, Japan

2. DAIICHI KIGENSO KAGAKU KOGYO CO., LTD., Kitahama 4-4-9, Chuo-ku, Osaka-shi 541-0041, Osaka, Japan

3. Faculty of Engineering, Yokohama National University, Tokiwadai 79-5, Hodogaya-ku, Yokohama 240-8501, Kanagawa, Japan

Abstract

This study developed advanced ceramic materials with both healing and decomposition functions using a metastable product generated under superheated steam. The developed composite material comprises ZrC particles dispersed in a yttria-stabilized zirconia (YSZ) matrix. After introducing a surface crack of approximately 120 μm on the composite specimen, it showed a complete strength recovery rate after one hour of heat treatment under superheated steam at 400 °C, while it exhibited a decomposition behavior after one hour of heat treatment in air at 400 °C. The XRD analysis of the heat-treated specimens showed that the final product was monoclinic ZrO2 under both steam and air conditions. In other words, full strength recovery in superheated steam was achieved by a chain reaction involving metastable intermediate products derived from H2O, unlike the reaction in air.

Publisher

MDPI AG

Subject

General Materials Science

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