Affiliation:
1. Department of Chemistry, Faculty of Natural Sciences, L.N. Gumilyov Eurasian National University, Astana 010000, Kazakhstan
2. Higher School of Natural Science, Margulan University, Pavlodar 140002, Kazakhstan
3. Eurasian Center for Innovative Development, Astana 010000, Kazakhstan
4. Department of Science, L.N. Gumilyov Eurasian National University, Astana 010000, Kazakhstan
Abstract
The given research employs high-resolution air quality monitoring and contemporary statistical methods to address gaps in understanding the urban air pollution in Pavlodar, a city with a significant industrial presence and promising touristic potential. Using mobile air quality sensors for detailed spatial data collection, the research aims to quantify concentrations of particulate matter (PM2.5, PM10), carbon monoxide (CO), nitrogen dioxide (NO2), sulfur dioxide (SO2), and ground-level ozone (O3); assess their distribution; and identify key influencing factors. In this study, we employed Geographic Information Systems (GISs) for spatial analysis, integrating multi-level B-spline interpolation to model spatial variability. Correlation analysis and structural equation modeling were utilized to explore the relationships between variables, while regression analysis was conducted to quantify these relationships. These techniques were crucial for accurately mapping and interpreting spatial patterns and their underlying factors. The study identifies PM2.5 and NO2 as the primary contributors to air pollution in Pavlodar, with NO2 exceeding the 24 h threshold in 87.38% of locations and PM2.5 showing the highest individual air quality index (AQI) in 75.7% of cases. Correlation analysis reveals a positive association between PM2.5 and AQI and a negative correlation between NO2 and AQI, likely due to the dominant influence of PM2.5 in AQI calculations. Structural equation modeling (SEM) further underscores PM2.5 as the most significant impactor on AQI, while NO2 shows no significant direct impact. Humidity is positively correlated with AQI, though this relationship is context-specific to seasonal patterns observed in May. The sectoral analysis of landscape indices reveals weak correlations between the green space ratio (GSR) and air quality, indicating that while vegetation reduces pollutants, its impact is minimal due to urban planting density. The road ratio (RR) lacks sufficient statistical evidence to draw conclusions about its effect on air quality, possibly due to the methodology used. Spatial variability in pollutant concentrations is evident, with increasing PM2.5, PM10, and AQI towards the east-northeast, likely influenced by industrial activities and prevailing wind patterns. In contrast, NO2 pollution does not show a clear geographic pattern, indicating vehicular emissions as its primary source. Spatial interpolation highlights pollution hotspots near industrial zones, posing health risks to vulnerable populations. While the city’s overall AQI is considered “moderate”, the study highlights the necessity of implementing measures to improve air quality in Pavlodar. This will not only enhance the city’s attractiveness to tourists but also support its sustainable development as an industrial center.
Funder
Science Committee of the Ministry of Science and Higher Education of the Republic of Kazakhstan
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