In Situ Observations Reveal the Five-fold Twin-Involved Growth of Gold Nanorods by Particle Attachment

Author:

Sun Qi12,Boddapati Loukya3ORCID,Wang Linan2,Li Junjie24ORCID,Deepak Francis Leonard3

Affiliation:

1. School of Semiconductor Science and Technology, South China Normal University, Foshan 528225, China

2. Research Center for Crystal Materials, CAS Key Laboratory of Functional Materials and Devices for Special Environments, Xinjiang Technical Institute of Physics & Chemistry, CAS, Urumqi 830011, China

3. Nanostructured Materials Group, International Iberian Nanotechnology Laboratory (INL), Avenida Mestre Jose Veiga, 4715-330 Braga, Portugal

4. Center of Materials Science and Optoelectronics Engineering, University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

Crystallization plays a critical role in determining crystal size, purity and morphology. Therefore, uncovering the growth dynamics of nanoparticles (NPs) atomically is important for the controllable fabrication of nanocrystals with desired geometry and properties. Herein, we conducted in situ atomic-scale observations on the growth of Au nanorods (NRs) by particle attachment within an aberration-corrected transmission electron microscope (AC-TEM). The results show that the attachment of spherical colloidal Au NPs with a size of about 10 nm involves the formation and growth of neck-like (NL) structures, followed by five-fold twin intermediate states and total atomic rearrangement. The statistical analyses show that the length and diameter of Au NRs can be well regulated by the number of tip-to-tip Au NPs and the size of colloidal Au NPs, respectively. The results highlight five-fold twin-involved particle attachment in spherical Au NPs with a size of 3–14 nm, and provide insights into the fabrication of Au NRs using irradiation chemistry.

Funder

High-level Talent Project of Xinjiang Uygur Autonomous Region

National Natural Science Foundation of China

Xinjiang Key Laboratory of Electronic Information Materials and Devices

Publisher

MDPI AG

Subject

General Materials Science,General Chemical Engineering

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