Affiliation:
1. Post-Graduation Program in Environmental and Sanitary Engineering (PPGEAS), Federal University of Goiás, Goiânia 74000-000, Brazil
2. Post-Graduation Program in Environmental Sciences (CIAMB), Federal University of Goiás, Goiânia 74000-000, Brazil
Abstract
Low concentrations of fluoride (F−) in drinking water are beneficial for oral health, but the natural occurrence of high F− content has been reported in various groundwater sources, posing a continuous ingestion threat to humans. The utilization of biochar (BC) produced from residual biomass has emerged as a technically, economically, and environmentally sustainable alternative for fluoride removal through adsorption. Therefore, this study aimed to investigate the physicochemical characteristics of BC derived from coffee grounds and the influence of various factors on the adsorption process of F− in aqueous media, including pH, adsorbent dosage, contact time, temperature, and initial F− concentration. The BC exhibited a surface area of 12.94 m2·g−1 and a pore volume of 0.0349 cm3·g−1. The adsorption process was strongly pH dependent, demonstrating a significant decline in performance as pH increased from 2.0 onwards. The majority of F− removal occurred within the first 5 min, reaching adsorption equilibrium after 1 h of testing, regardless of the initial F− concentration employed. The data fitting to the Webber–Morris model indicated a two-step adsorption process on BC, with the first step being external surface sorption and the second step being intra-articular diffusion. The process was determined to be endergonic, and the data satisfactorily matched both the Freundlich and Langmuir models, with a qm of 0.53 mg·L−1 (T = 55 °C), indicating the predominance of physisorption. The findings suggest the potential of coffee grounds for BC production; nevertheless, surface structure modifications are necessary to enhance F− affinity and subsequently improve adsorption capacity.
Funder
Coordenação de Aperfeiçoamento de Pessoal de Nível Superior—CAPES
Subject
Management, Monitoring, Policy and Law,Nature and Landscape Conservation
Reference94 articles.
1. Jullien, S. (2021). Prophylaxis of Caries with Fluoride for Children under Five Years. BMC Pediatrics, 351.
2. Fluoride in Drinking Water and Skeletal Fluorosis: A review of the global impact;Srivastava;Curr. Environ. Health Rep.,2020
3. WHO—World Heath Organization (2006). Guidelines for Drinking-Water Quality, World Health Organization.
4. Adsorption of Fluoride onto Mixed Rare Earth Oxides;Raichur;Sep. Purif. Technol.,2001
5. Anomalias de Flúor nas Águas Subterrâneas do Estado de São Paulo;Ezaki;Rev. Inst. Geológico,2016
Cited by
1 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献