The Surface Structure Change of Columbite-(Fe) Dissolution in H2SO4

Abstract

The mineral surface structure and ions’ interaction were of significant interest to understanding mineral dissolution and reaction. In this study, X-ray photoemission spectroscopy combined with ICP emission spectrometer was used to investigate the influence of the leaching reaction conditions of 8 M dilute sulfuric acid and 12 M concentrated sulfuric acid on the surface chemical composition, chemical (valence) state and ion distribution of Columbite-(Fe) (FeNb2O6). The binding energy of the cations (Fe, Nb) bonding with different anions (O2−, SO42−) and the ratio of Fe3+/Fe2+ oxidation–reduction provided direct understanding of Fe and Nb releasing from the mineral surface during leaching. The results showed that the binding energy of the Nb5+-O bond was much smaller than that of Nb5+-SO4, and the binding energy decreased in sequence as Nb5+-O < Fe2+-O < Fe3+-O and increased in sequence as Fe3+-SO4 < Fe2+-SO4 < Nb5+-SO4. The mineral surface reaction during the leaching could be expressed with the formula: Fe-O + H2SO4 → Fe-SO4 + H2O, Nb-O + H2SO4 → Nb-SO4 + H2O. The results also revealed that Nb dissolution from Columbite-(Fe) occurred more easily compared to Fe. Nb dissolution from the mineral was owed to the content of H+ in solution, and increasing the H+ concentration could promote the dissolution. For Fe dissolution from the mineral, the oxidation potential could play an effective role in enhancement dissolution.