Provenance and Paleoenvironmental Studies of Cretaceous African and South American Kaolins: Similarities and Differences

Abstract

The African and South American continents are of great interest in continental drift studies. Hence, this study assesses the possible correlations in the provenance and paleoenvironment of selected Cretaceous Nigerian and Cameroonian (in Africa), and Argentine and Brazilian (in South America) kaolins through an analysis of their mineralogical and geochemical characteristics. On the basis of their mineralogical composition, the Nigerian Lakiri and Brazilian soft Capim River kaolins are predominantly characterised as pure kaolins, whereas the kaolins from Cameroon (except for Yatchika) and Argentina are mainly considered as sandy kaolins. The present study revealed that the Brazilian soft Capim River kaolin had the highest kaolinite structural order, whilst the Argentine Santa Cruz kaolin had the least. The kaolins from Nigeria, Cameroon, and Argentina were dominated by subhedral to anhedral kaolinite crystals relative to the Brazilian kaolin, which possess more euhedral kaolinite crystals. The kaolins were formed by the intense weathering of intermediate to felsic rocks under anoxic conditions, which is consistent with the structural framework of the basins. The average paleotemperatures obtained for the kaolins (except for the one from Santa Cruz) indicates that the paleoweathering took place under tropical climates.