Thin Film Gas Sensors Based on Planetary Ball-Milled Zinc Oxide Nanoinks: Effect of Milling Parameters on Sensing Performance

Abstract

Planetary ball-milled zinc oxide (ZnO) nanoparticle suspensions (nanoinks) were used to produce thin film chemiresistive gas sensors that operate at room temperature. By varying milling or grinding parameters (speed, time, and solvent) different thin film gas sensors with tunable particle sizes and porosity were fabricated and tested with dry air/oxygen against hydrogen, argon, and methane target species, in addition to relative humidity, under ambient light conditions. Grinding speeds of up to 1000 rpm produced particle sizes and RMS thin film roughness below 100 nm, as measured by atomic force and scanning electron microscopy. Raman spectroscopy, photoluminescence, and X-ray analysis confirmed the purity and structure of the resulting ZnO nanoparticles. Gas sensor response at room temperature was found to peak for nanoinks milled at 400 rpm and for 30 min in ethylene glycol and deionized water, which could be correlated to an increased film porosity and enhanced variation in electron concentration resulting from adsorption/desorption of oxygen ions on the surfaces of ZnO nanoparticles. Sensor response and dynamic behavior was found to improve as the temperature was increased, peaking between 100 and 150 °C. This work demonstrates the use of low-cost PBM nanoinks as the active materials for solution-processed thin film gas/humidity sensors for use in environmental, medical, food packaging, laboratory, and industrial applications.