Using Geochemical and Environmental Isotopic Tracers to Evaluate Groundwater Recharge and Mineralization Processes in Qena Basin, Eastern Nile Valley, Egypt

Abstract

The Qena basin (16,000 km2) represents one of the largest dry valleys located in the arid Eastern Desert of Egypt. Groundwater resources in this watershed are scarce due to limited recharge from annual precipitation. Hydrogeochemistry and environmentally stable isotopes were utilized to determine the main sources of recharge and geochemical processes affecting groundwater quality. The studied basin comprises three main groundwater aquifers: the Quaternary aquifer, the Post-Nubian aquifer (PNA) of the Paleocene-Eocene age, and the Nubian Sandstone aquifer (NSA) of the Lower Cretaceous age. Groundwater types vary from fresh to brackish groundwater. The groundwater salinity of the Quaternary aquifer ranges from 426 to 9975 mg/L with an average of 3191 mg/L, the PNA’s groundwater salinity ranges from 1134 to 6969 mg/L with an average of 3760 mg/L, and the NSA’s groundwater salinity ranges from 1663 to 1737 mg/L with an average of 1692 mg/L. The NSA’s groundwater is relatively depleted of stable isotopes’ signatures (ranges: δ18O from −9‰ to −4.81‰; δ2H from −71‰ to −33.22‰), whereas the Quaternary aquifer’s groundwater is relatively enriched (ranges: δ18O from −5.51 to +4.70‰; δ2H from −40.87 to +37.10‰). Geochemical and isotopic investigations reveal that the NSA groundwater is a paleo-water recharged in a cooler climate. In contrast, the upstream Quaternary groundwater receives considerable recharge from recent meteoric water and upward leakage from the artesian NSA. The downstream Quaternary aquifer in the delta of the Qena basin is composed of original groundwater mixed with recharge from the River Nile. Isotopic analysis confirms that the PNA’s groundwater recharge (ranges: δ18O from −5.90 to −0.10; δ2H −58.21 to −7.10‰) mainly originates from upward leakage from the NSA under the artesian condition and seepage from the upper unconfined Quaternary aquifer. NETPATH geochemical model results show that water–rock interaction, evaporation, and mixing are the main geochemical and physical processes controlling the groundwater quality. NSA groundwater has a significant regional extension and salinity suitable for use in expanding agricultural projects; it should be well managed for sustainable development.