Effect of Melamine Formaldehyde Resin Encapsulated UV Acrylic Resin Primer Microcapsules on the Properties of UV Primer Coating

Abstract

Ultra-Violet (UV) coatings are widely adaptable of substrates and produce low emissions of volatile organic compounds. UV coatings can extend service life by adding self-healing microcapsules that restore integrity after sustaining damage. In this study, UV coating was used as a core material; microcapsules were produced and added to the UV coating to enhance its self-healing property, providing a good protection for both the UV coating and the substrate. UV primer microcapsules were prepared with UV primer as the core material and melamine formaldehyde resin as the wall material. The UV primer containing more than 98.0% solids content was mainly composed of epoxy acrylic resin, polyester acrylic resin, trihydroxy methacrylate, trimethyl methacrylate, and photo initiator. The preparation process of the UV primer microcapsules was optimized. Further, the UV coating was prepared with better UV primer microcapsules, and the effects of the UV primer microcapsules alongside the comprehensive properties of the coating were studied. The best preparation process for the UV primer microcapsules was as follows: the wall-core mass ratio was 1:0.50, Triton X-100 and Span-20 as emulsifiers with an HLB value of 10.04, the microcapsule reaction temperature was 70 °C, and the reaction time of the was 3.0 h. When the quantity of the UV primer microcapsules increased in the coating, color difference ΔE of the coating increased, gloss decreased, transmittance decreased, elongation at break increased and then decreased, roughness increased, and self-healing rate first increased and then decreased. When the addition of the UV primer microcapsules reached 2.0%, the color difference ΔE of the coating was 1.71, the gloss was 106.63 GU, the transmittance was 78.80%, the elongation at break was 3.62%, the roughness was 0.204 μm, and the self-healing rate was 28.56%, which were the best comprehensive properties of the UV primer. To improve the comprehensive properties of the UV coatings, the UV coatings were modified by a microcapsule technology, which gave the UV coatings a better self-healing property. The application range of microcapsules for the UV coatings was broadened. Based on the previous research of microcapsules in UV coatings, the results further refined the study of the effects of adding self-healing microcapsules to UV coatings using the UV coating itself as the core material.