Assessment of the Biodegradability and Compostability of Finished Leathers: Analysis Using Spectroscopy and Thermal Methods

Author:

Vico Alberto1ORCID,Maestre-Lopez Maria I.2,Arán-Ais Francisca1ORCID,Orgilés-Calpena Elena1,Bertazzo Marcelo1,Marhuenda-Egea Frutos C.2

Affiliation:

1. Footwear Technological Institute (INESCOP), C/Alemania 102—Polígono Campo Alto, 03600 Elda, Spain

2. Department of Biochemistry and Molecular Biology and Agricultural Chemistry and Edafology, University of Alicante, Carretera San Vicente del Raspeig s/n, 03690 Alicante, Spain

Abstract

In this study, the biodegradation properties of leather treated with various finishing chemicals were evaluated in order to enhance the sustainability of leather processing. We applied advanced analytical techniques, including FT-IR, thermogravimetric analysis (TGA), and solid-state NMR spectroscopy. Leather samples treated with different polymers, resins, bio-based materials, and traditional finishing agents were subjected to a composting process under controlled conditions to measure their biodegradability. The findings revealed that bio-based polyurethane finishes and acrylic wax exhibited biodegradability, while traditional chemical finishes like isocyanate and nitrocellulose lacquer showed moderate biodegradation levels. The results indicated significant differences in the biodegradation rates and the impact on plant germination and growth. Some materials, such as black pigment, nitrocellulose lacquer and wax, were beneficial for plant growth, while others, such as polyurethane materials, had adverse effects. These results support the use of eco-friendly finishes to reduce the environmental footprint of leather production. Overall, this study underscores the importance of selecting sustainable finishing chemicals to promote eco-friendly leather-manufacturing practices.

Funder

Instituto Valenciano de Competitividad Empresarial

Publisher

MDPI AG

Reference68 articles.

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3. (2024, March 07). Leather Industry Insight—Pergamena. Available online: https://www.pergamena.net/blog/v3piynz4zg9ysubox7b1r3zszwrfx8.

4. A Sustainable and Cleaner Speedy Tanning System Based on Condensed Tannins Catalyzed by Laccase;Qiang;J. Clean. Prod.,2018

5. Zeolites as Sustainable Alternatives to Traditional Tanning Chemistries;Wise;Green. Chem.,2023

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