Elastomeric Fire and Heat-Protective Materials Containing Functionally Active Microheterogeneous Systems

Author:

Kochetkov Vladimir G.12,Kryukova Daria A.12,Urzhumov Daniil A.12,Novopoltseva Oksana M.1,Keibal Natalia A.1,Burmistrov Vladimir2ORCID,Kablov Victor F.1

Affiliation:

1. Department of Chemical Technology of Polymers and Industrial Ecology, Volzhsky Polytechnic Institute (Branch) of Volgograd State Technical University, 42a Engelsa St., Volzhsky 404121, Russia

2. Department of Organic Chemistry, Volgograd State Technical University, 28 Lenina Avenue, Volgograd 400005, Russia

Abstract

This research aims to explore how functionally active structures affect the physical, mechanical, thermal, and fire-resistant properties of elastomeric compositions using ethylene–propylene–diene rubber as a base. The inclusion of aluminosilicate microspheres, microfibers, and a phosphorus–boron–nitrogen–organic modifier in these structures creates a synergistic effect, enhancing the material’s heat-insulating properties by strengthening coke and carbonization processes. This results in a 12–19% increase in heating time for unheated sample surfaces and a 6–17% increase in residual coke compared to existing analogs. Microspheres help counteract the negative impact of microfibers on composition density and thermal conductivity, while the phosphorus–boron–containing modifier allows for controlling the formation of the coke layer.

Funder

Ministry of science and higher education of Russian Federation

Scholarship of the President of the Russian Federation to young scientists and Postgraduates

Publisher

MDPI AG

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