Mechanical, Fire, and Electrical Insulation Properties of Polyurethane Fly Ash Composites

Author:

Shivakumar Kunigal N.1,Kenchappa Bharath1ORCID,Imran Kazi A.2

Affiliation:

1. Department of Mechanical Engineering, Center for Composite Materials Research, North Carolina A&T State University, 1601 East Market St., Greensboro, NC 27401, USA

2. SUNY Polytechnic Institute, 100 Seymour Rd., Utica, NY 13502, USA

Abstract

This paper demonstrates that ash composites, comprising fly ash and polyurethane, can be used to develop value-added products that exhibit an effective decrease in the leaching of coal ash inorganics to less than one-third of the Environmental Protection Agency (EPA)’s maximum contaminant level (MCL) when soaked in a water circulation system for 14 months. Furthermore, the composite blocks remain safe even with ruptured surfaces. The concept of encapsulating fly ash within ash composites by using a polar polymer to bind the fine inorganic particles, mimicking how nature does it in the original unburned coal, ensures the safety of the composite. The ash composites can be formulated to have designed mechanical, fire, and electrical properties by controlling the formulation and the density. The properties of typical density composites were produced, measured, and compared with commercial materials. This paper also demonstrates that ash composite technology can be extended to coal ash stored in ponds. Finally, a typical electric utility box cover was designed, fabricated, and test validated. The box cover has less than one-half the weight of the original box cover for the same design limits. Finally, the benefits of this ash-composite technology for product manufacturers, society, and ash producers are summarized.

Funder

North Carolina Department of Environmental Quality

Publisher

MDPI AG

Reference25 articles.

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2. American Coal Ash Association (2023, August 10). Ash at Work, Applications, Science, and Sustainability of Coal Ash. Available online: https://acaa-usa.org/wp-content/uploads/2023/06/ASH-2023-1.pdf.

3. Fly ash composites, a step toward pond ash composites;Shivakumar;Coal Combust. Gasif. Prod.,2019

4. Shivakumar, K. (2016, January 3–6). Transfer of Eco-Core Technology to Coal Ash Composites Products. Proceedings of the 31st International Conference on Solid Waste, Philadelphia, PA, USA.

5. Thorneloe, S., Kosson, D., Helms, G., and Garrabrants, A. (2009, January 5–9). Improved Leaching Test Methods for Environmental Assessment of Coal Ash and Recycled Materials Used in Construction. Proceedings of the Sardinia 2009, Twelfth International Waste Management and Landfill Symposium, Cagliari, Italy.

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