The Occurrence and Chemical Composition of Bismuth-Bearing Minerals in the Niuxingba-Liumukeng Ag-Pb-Zn Deposit, Jiangxi Province, South China

Author:

Yue Qiuyu12,Zhai Degao12,Zhao Gang12,Zhao Qingqing12,Liu Jiajun12ORCID

Affiliation:

1. State Key Laboratory of Geological Processes and Mineral Resources, School of Earth Sciences and Resources, China University of Geosciences Beijing, Beijing 100083, China

2. Frontiers Science Center for Deep-Time Digital Earth, China University of Geosciences Beijing, Beijing 100083, China

Abstract

The Niuxingba-Liumukeng deposit, located in the Yinkeng ore field (Jiangxi province, South China), is a typical Ag-Pb-Zn deposit hosted in the Yudu-Ganxian metallogenic belt. Based on the field investigation and mineralogical studies, the mineralization of this deposit can be divided into three stages: quartz-pyrite-arsenopyrite stage (I), quartz-galena-sphalerite-sulfosalt stage (II), and quartz-carbonate stage (III), with stage II being the main Ag mineralization stage. In this contribution, we reported the occurrence of bismuth-bearing minerals in this hydrothermal deposit and its implications for ore formation. Based on the results of electron microprobe analyses, we infer that the dominant occurrence of bismuth at Niuxingba-Liumukeng is primarily marked by solid solutions within the crystal lattice of galena and as visible independent bismuth-bearing minerals. The independent bismuth minerals consist of berryite [Pb3(Ag,Cu)5Bi7S16], emplectite (CuBiS2), and aikinite (PbCuBiS3). Most bismuth minerals replace chalcopyrite or fill in the cracks of pyrite and chalcopyrite. Meanwhile, we found a large number of Bi-bearing minerals closely coexisting with Ag-bearing minerals, indicating that bismuth may have played a crucial role in silver deposition from hydrothermal fluids. We considered that the existence of bismuth-rich melts associated with the ore-forming hydrothermal systems could help to promote the enrichment and precipitation of silver to form economic ores.

Funder

National Natural Science Foundation of China

he Fundamental Research Funds for the Central Universities

Publisher

MDPI AG

Subject

Geology,Geotechnical Engineering and Engineering Geology

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