Capacity of River Valleys to Retain Nutrients from Surface Runoff in Urban and Rural Areas (Southern Poland)

Abstract

Studies on water quality are necessary, as catchments of small watercourses are exposed to anthropogenic influences associated with agricultural activities, settlement, transport and other undertakings, leading to water pollution. There has been insufficient research performed on the valley’s ability to retain nutrients during floods, contributing to water accumulation. The main object of the study was to identify the retention capacity of river valleys under various aspects of human urbanization. To represent soil water retention, the Soil Conservation Service Curve Number (SCS-CN) method was used. Spatiotemporal autoregressive models were exploited to investigate the relationship between pollutants in precipitation and surface water in rivers. In contrast, multivariate analysis was used to identify and reveal patterns of land use for specific chemical compounds in the headwaters. The canonical-correlation analysis (CCA) showed that Mg+2 and Ca+2 cations in rainwater and surface waters play the main roles in the geochemical cycle in urban and rural areas. In the urban catchment area, the strongest relations were found for NO3−, K+ and Na+. The average NO3− concentration in urban headwater was 8.3 mg·dm−3, the highest in the study area. The relationship between NO3− concentration in headwater and rainwater was found for all study catchments using spatial autoregression (SAR). High concentrations of SO42− in surface water have been identified in urban areas. Severe water erosion raises the risk of nutrient leaching in soils prone to surface runoff. As a consequence of low soil permeability and urbanization, retention capacity is significantly reduced in areas with low soil permeability. Land development plans should take spatial retention capacity into consideration. To ensure that large reservoirs can retain water in the face of climate change, riparian buffer zones (protective zones in valleys for small water bodies as well as Nature-based Solution) are important.