Improvement of the Piezoresistive Behavior of Poly (vinylidene fluoride)/Carbon Nanotube Composites by the Addition of Inorganic Semiconductor Nanoparticles

Abstract

Conductive polymer composites (CPCs), obtained by incorporating conductive fillers into a polymer matrix, are suitable for producing strain sensors for structural health monitoring (SHM) in infrastructure. Here, the effect of the addition of inorganic semiconductor nanoparticles (INPs) to a poly (vinylidene fluoride) (PVDF) composite filled with multi-walled carbon nanotubes (MWCNTs) on the piezoresistive behavior is investigated. INPs with different morphologies and sizes are synthesized by a hydrothermal method. The added inorganic oxide semiconductors showed two distinct morphologies, including different phases. While particles with flower-like plate morphology contain phases of orth-ZnSnO3 and SnO, the cauliflower-like nanoparticles contain these metal oxides and ZnO. The nanoparticles are characterized by field-emission scanning electron microscopy (FE-SEM) and X-ray diffraction (XRD), and the nanocomposites by Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), differential scanning calorimetry (DSC), and thermogravimetric analysis (TGA). Cyclic tensile testing is applied to determine the strain-sensing behavior of PVDF/1 wt% MWCNT nanocomposites with 0–10 wt% inorganic nanoparticles. Compared to the PVDF/1 wt% MWCNT nanocomposite, the piezoresistive sensitivity is higher after the addition of both types of nanoparticles and increases with their amount. Thereby, nanoparticles with flower-like plate structures improve strain sensing behavior slightly more than nanoparticles with cauliflower-like structures. The thermogravimetric analysis results showed that the morphology of the semiconductor nanoparticles added to the PVDF/MWCNT matrix influences the changes in thermal properties.