Abstract
The possibility of analysis using charge curve fitting in constant potential coulometric mode instead of using a calibration plot is explored, for the first time. The results are compared with the analysis based on the use of a calibration plot. A Ca2+ ion-selective electrode, with and without an electronic capacitor in series, is used as a model system in pure solutions of CaCl2. Both techniques delivered good results (error within 2%) when the final and the initial concentration values differed by not more than three times. Larger differences result in 10–25% error. The presence of an electronic capacitor in the measurement circuit and in series with the electrode, allows for significantly faster response.
Funder
Russian Foundation for Basic Research
Subject
Electrical and Electronic Engineering,Biochemistry,Instrumentation,Atomic and Molecular Physics, and Optics,Analytical Chemistry
Cited by
7 articles.
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