Effect of Alkali Salts on the Hydration Process of Belite Clinker

Abstract

Belite-rich cement is a low carbon footprint binder. However, its use is accompanied by a low initial rate of hydration. This can be partially eliminated by grinding to a high specific surface or through the addition of admixtures (mineralizators or activators). The influence of alkaline activators CaSO4, Na2SO4 and Na2CO3 (in the amount of 5 wt.% related to the clinker weight) on the hydration course, as well as the quantity of hydration products in belite-rich cements, were investigated in this paper. Belite-rich clinker was laboratory-synthetized and ground together with activators to prepare various belite-rich cements. Next, the hydration kinetics and the hydrated phase assemblage were investigated using isothermal calorimetry, X-ray powder diffraction and thermogravimetric and differential thermal analyses. The use of selected admixtures allowed us to obtain belite-rich cements with higher hydraulic activity in the initial period.