A Study on the Impermeability of Nanodispersible Modified Bentonite Based on Colloidal Osmotic Pressure Mechanisms and the Adsorption of Harmful Substances

Abstract

With the growing demands of human beings, sanitary landfill, along with the increase in landfill depth and leachate water pressure, has put forward new and higher requirements for the impermeable layer. In particular, it is required to have a certain adsorption capacity of harmful substances from the perspective of environmental protection. Hence, the impermeability of polymer bentonite–sand mixtures (PBTS) at different water pressure and the adsorption properties of polymer bentonite (PBT) on contaminants were investigated through the modification of PBT using betaine compounded with sodium polyacrylate (SPA). It was found that the composite modification of betaine and SPA could reduce the average particle size of PBT dispersed in water (reduced to 106 nm from 201 nm) and enhance the swelling properties. As the content of SPA increased, the hydraulic conductivity of PBTS system decreases and the permeability resistance improves, while the resistance to external water pressure increases. It is proposed a concept of the potential of osmotic pressure in a constrained space to explain the impermeability mechanism of PBTS. The potential of osmotic pressure obtained by linear extrapolation of the trendline of colloidal osmotic pressure versus mass content of PBT could represent the external water pressure that the PBT resist. Additionally, the PBT also has a high adsorption capacity for both organic pollutants and heavy metal ions. The adsorption rate of PBT was up to 99.36% for phenol; up to 99.9% for methylene blue; and 99.89%, 99.9%, and 95.7% for low concentrations of Pb2+, Cd2+, and Hg+, respectively. This work is expected to provide strong technical support for the future development in the field of impermeability and removal of hazardous substances (organic and heavy metals).