Catalytic Transfer Hydrogenolysis Reactions for Lignin Valorization to Fuels and Chemicals

Abstract

Lignocellulosic biomass is an abundant renewable source of chemicals and fuels. Lignin, one of biomass main structural components being widely available as by-product in the pulp and paper industry and in the process of second generation bioethanol, can provide phenolic and aromatic compounds that can be utilized for the manufacture of a wide variety of polymers, fuels, and other high added value products. The effective depolymerisation of lignin into its primary building blocks remains a challenge with regard to conversion degree and monomers selectivity and stability. This review article focuses on the state of the art in the liquid phase reductive depolymerisation of lignin under relatively mild conditions via catalytic hydrogenolysis/hydrogenation reactions, discussing the effect of lignin type/origin, hydrogen donor solvents, and related transfer hydrogenation or reforming pathways, catalysts, and reaction conditions.