A Study of the Structure and Physicochemical Properties of the Mixed Basicity Iron Ore Sinter

Author:

Dmitriev Andrey N.1ORCID,Vyaznikova Elena A.1,Vitkina Galina Yu.1,Karlina Antonina I.2ORCID

Affiliation:

1. Laboratory of Pyrometallurgy of Reduction Processes, Institute of Metallurgy of the Ural Branch of the Russian Academy of Sciences, 101 Amundsen St., 620016 Ekaterinburg, Russia

2. Stroytest Research and Testing Center, Moscow State University of Civil Engineering, 26, Yaroslavskoye Shosse, 129337 Moscow, Russia

Abstract

To study the influence of sinter basicity on the microstructure, phase composition, and physicochemical and metallurgical properties, samples of agglomerates with different basicities were sintered and investigated. A comprehensive study of the structure, composition, chemical, and metallurgical properties of the sinter was conducted, and the optimum values for these properties were determined. The results of the mineralogical transformations that occurred during the sintering process are also presented. The magnetite contained in the concentrate partially dissolves in the silicate component and flux during agglomeration, forming a complex silicate SFCA with the general formula M14O20 (M–Ca, Si, Al, and Mg), which is the binder of the ore phases of the agglomerate. The proportion of ferrosilicates of calcium and aluminum in the sinter depends on the basicity of the sinter charge, and the morphology of the SFCA phase depends on the cooling rate of the sinter. The more CaO in the sinter charge, the more SFCA phase is formed in the sinter, and slow cooling results in the growth of large lamellar and dendritic SFCA phases.

Funder

the State Assignment of the Institute of metallurgy of the Ural Branch of the Russian Academy of Sciences

Publisher

MDPI AG

Subject

Materials Chemistry,Chemistry (miscellaneous),Electronic, Optical and Magnetic Materials

Reference44 articles.

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4. Park, J., Kim, E., Suh, I.-k., and Lee, J. (2022). A Short Review of the Effect of Iron Ore Selection on Mineral Phases of Iron Ore Sinter. Minerals, 12.

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