A New Organic Conductor of Tetramethyltetraselenafulvalene (TMTSF) with a Magnetic Dy(III) Complex-Reference-Cited by-同舟云学术

A New Organic Conductor of Tetramethyltetraselenafulvalene (TMTSF) with a Magnetic Dy(III) Complex

Published:2023-03-06 Issue:3 Volume:9 Page:77
ISSN:2312-7481
Container-title:Magnetochemistry
language:en
Short-container-title:Magnetochemistry

Author:

Wan Qingyun¹²^ORCID,Wakizaka Masanori¹^ORCID,Zhang Haitao¹,Shen Yongbing³,Funakoshi Nobuto¹^ORCID,Che Chi-Ming²,Takaishi Shinya¹^ORCID,Yamashita Masahiro¹⁴

Affiliation:

1. Department of Chemistry, Graduate School of Science, Tohoku University, Aramaki-Aza-Aoba, Aoba-ku, Sendai 980-8578, Japan

2. Department of Chemistry, State Key Laboratory of Synthetic Chemistry, HKU-CAS Joint Laboratory on New Materials, The University of Hong Kong, Pokfulam Road, Hong Kong, China

3. Frontier Institute of Science and Technology (FIST), State Key Laboratory for Mechanical Behavior of Materials, MOE Key Laboratory for Nonequilibrium Synthesis of Condensed Matter, Xi’an Jiaotong University, 99 Yanxiang Road, Xi’an 710054, China

4. School of Materials Science and Engineering, Nankai University, Tianjin 300350, China

Abstract

A new molecular conductor of (TMTSF)5[Dy(NCS)4(NO3)2]CHCl3 was prepared using the electrochemical oxidation method. The complex crystallizes in the Cmc21 (36) space group, where the partially-oxidized TMTSF molecules form a 1D (one-dimensional) column structure. The crystal shows a semiconducting behavior with a room temperature conductivity of 0.2 S·cm−1 and an activation energy of 34 meV at ambient pressure.

Funder

JSPS KAKENHI

National Natural Science Foundation of China

111 projects

Publisher

MDPI AG

Subject

Materials Chemistry,Chemistry (miscellaneous),Electronic, Optical and Magnetic Materials

Link

https://www.mdpi.com/2312-7481/9/3/77/pdf

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